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Diffusion Fundamentals
Article . 2007 . Peer-reviewed
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QENS and the benefit of diffusion measurements over different length scales

Authors: Jobic, Hervé;

QENS and the benefit of diffusion measurements over different length scales

Abstract

The quasi-elastic neutron scattering (QENS) technique was first used to derive self-diffusivities of hydrocarbons in zeolites, but transport diffusivities of deuterated molecules and of molecules which do not contain hydrogen atoms can now be measured. The technique allows to probe diffusion over length scales ranging from an Å to hundreds of Å. The mechanism of diffusion can thus be followed from the elementary jumps between adsorption sites to Fickian diffusion. Since the space and time scales of the neutron techniques match closely the ones covered by molecular simulations, one expects, and usually finds, good agreement between neutrons and simulations. The neutron data give therefore reference values, so that lower values obtained by other techniques measuring diffusion over longer length scales have to be explained by additional transport barriers.

Country
Germany
Keywords

diffusion, transport, ddc:530, [SDE.ES] Environmental Sciences/Environment and Society, [CHIM.CATA] Chemical Sciences/Catalysis, Diffusion, Transport, info:eu-repo/classification/ddc/530

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
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