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Direct measurement of key exciton properties: Energy, dynamics, and spatial distribution of the wave function

Authors: Dong, Shuo; Puppin, Michele; Pincelli, Tommaso; Beaulieu, Samuel; Christiansen, Dominik; Hübener, Hannes; Nicholson, Christopher W.; +11 Authors

Direct measurement of key exciton properties: Energy, dynamics, and spatial distribution of the wave function

Abstract

Abstract Excitons, Coulomb‐bound electron–hole pairs, are the fundamental excitations governing the optoelectronic properties of semiconductors. Although optical signatures of excitons have been studied extensively, experimental access to the excitonic wave function itself has been elusive. Using multidimensional photoemission spectroscopy, we present a momentum‐, energy‐, and time‐resolved perspective on excitons in the layered semiconductor WSe 2 . By tuning the excitation wavelength, we determine the energy–momentum signature of bright exciton formation and its difference from conventional single‐particle excited states. The multidimensional data allow to retrieve fundamental exciton properties like the binding energy and the exciton–lattice coupling and to reconstruct the real‐space excitonic distribution function via Fourier transform. All quantities are in excellent agreement with microscopic calculations. Our approach provides a full characterization of the exciton properties and is applicable to bright and dark excitons in semiconducting materials, heterostructures, and devices. Key points The full life cycle of excitons is recorded with time‐ and angle‐resolved photoemission spectroscopy. The real‐space distribution of the excitonic wave function is visualized. Direct measurement of the exciton‐phonon interaction.

Keywords

Condensed Matter - Materials Science, quasi‐particle interactions, Science, Q, Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences, semiconductors, time‐resolved photoemission spectroscopy, exciton physics, condensed matter physics, condensed matter physics; exciton physics; many-body physics; time-resolved photoemission spectroscopy; ultrafast dynamics; quasi-particle interactions; semiconductors, many‐body physics

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
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