This work studies the activity of activated CaO as a catalyst in the production of biodiesel by transesterification of triglycerides with methanol. Three basic aspects were investigated: the role of H2O and CO2 in the deterioration of the catalytic performance by contact with room air, the stability of the catalyst by reutilization in successive runs and the heterogeneous character of the catalytic reaction. The characterization by X-ray diffraction (XRD), evolved gas analysis by mass spectrometry (EGA-MS) during heating the sample under programmed temperature, X-ray photoelectron (XPS) and Fourier transform-infrared (FT-IR) spectroscopies allowed to concluding that CaO is rapidly hydrated and carbonated by contact with room air. Few minutes are enough to chemisorb significant amount of H2O and CO2. It is demonstrated that the CO2 is the main deactivating agent whereas the negative effect water is less important. As a matter of fact the surface of the activated catalyst is better described as an inner core of CaO particles covered by very few layers of Ca(OH)2. The activation by outgassing at temperatures ≥973 K are required to revert the CO2 poisoning. The catalyst can be reused for several runs without significant deactivation. The catalytic reaction is the result of the heterogeneous and homogeneous contributions. Part of the reaction takes place on basic sites at the surface of the catalyst, the rest is due to the dissolution of the activated CaO in methanol that creates homogeneous leached active species. © 2007 Elsevier B.V. All rights reserved.

Financial support from European Commission Sixth Framework Programme (under project BIOCARD, contract no. 019829), Spanish Ministry of Education and Science (MAT2003-08348-C04-01 project) and Regional Government of Madrid (GR/AMB/0686/2004 project) is gratefully acknowledged. D.M. A. and M.D. Z. P. thank to the Regional Government of Madrid and the Spanish Ministry of Education and Science, respectively, for their fellowships.

Peer reviewed