Abstract We present the discovery of Boötes V, a new ultra-faint dwarf galaxy (UFD) candidate. This satellite is detected as a resolved overdensity of stars during an ongoing search for new Local Group dwarf galaxy candidates in the UNIONS photometric data set. It has a physical half-light radius of 26.9 − 5.4 + 7.5 pc, a V-band magnitude of −4.5 ± 0.4 mag, and resides at a heliocentric distance of approximately 100 kpc. We use Gaia DR3 astrometry to identify member stars, characterize the systemic proper motion, and confirm the reality of this faint stellar system. The brightest star in this system was followed up using Gemini GMOS-N long-slit spectroscopy and is measured to have a metallicity of [Fe/H] = −2.85 ± 0.10 dex and a heliocentric radial velocity of v r = 5.1 ± 13.4 km s−1. Boötes V is larger (in terms of scale radius), more distant, and more metal-poor than the vast majority of globular clusters. It is likely that Boötes V is an UFD, though future spectroscopic studies will be necessary to definitively classify this object.