Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Dépôt Institutionel ...arrow_drop_down
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
addClaim

Design and fabrication of instruments for broadband spectroscopy of cold molecules

Authors: Libert, Alexis;

Design and fabrication of instruments for broadband spectroscopy of cold molecules

Abstract

The perfect instrument in spectroscopy measures spectra with high-resolution, high-sensitivity and in a small amount of time over a broad spectral range. Fourier-transform spectrometers (FTS) allow for both high resolution and broadband measurements thanks to their multiplex advantage. By coupling the light source to an optical cavity, the sensitivity of the instrument is considerably increased since the interaction length of the light with the sample is increased by several orders of magnitude (reaching kilometric interaction lengths). The use of frequency combs allows to increase the precision of the measurement and to surpass the maximum resolution of conventional FTS. Finally, when performing spectroscopy of complex molecules in the gas phase at high resolution, spectra are highly congested because many energy levels are populated, allowing a great number of transitions to occur. This results in difficulties to assign each transition to its corresponding energy levels. The advent of the buffer gas cooling technique that permits to cool down atoms and molecules to cryogenic temperatures opens the door to go beyond the state of the art in terms of molecular complexity with the study of large and heavy molecules at relatively high frequencies (NIR,VIS). The objective of this PhD thesis is to present the design, the fabrication and the characterization of an instrument that will ultimately embody all these features, allowing for the study of large molecules in the gaseous phase in the near-infrared and visible regions of the light spectrum. In its final form, it will consist of a frequency comb as a light source, a FTS as a spectrum analyzer and a buffer gas cooling setup in order to perform the spectroscopy of cold molecules, the required sensitivity being achieved by making the measurements within an optical cavity. (SC - Sciences) -- UCL, 2022

Country
Belgium
Related Organizations
Keywords

Fourier transform spectrometer, Methanol, Cavity, Homemade, Laser, Water, Optics, Cold head, Molecular spectroscopy, Stabilization, Sensitive, Femtosecond laser, Data processing, Frequency comb, Photonics, Buffer gas cooling, CRDS, Cold molecules, Cavity ringdown spectroscopy, Baseline retrieval, High resolution, Photonic fiber, Supercontinuum, Cavity-enhanced absorption spectroscopy

  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    0
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Green
Related to Research communities