Exploring Electrochemically Mediated ATRP of Styrene
Copyright policy )Exploring Electrochemically Mediated ATRP of Styrene
Electrochemically mediated atom transfer radical polymerization (eATRP) of styrene was studied in detail by using CuBr2/TPMA (TPMA = tris(2-pyridylmethyl)amine) as a catalyst. Redox properties of various Cu(II) species were investigated in CH3CN, dimethylformamide (DMF), and dimethyl sulfoxide (DMSO) both in the absence and presence of 50% (v/v) styrene. This investigation together with preliminary eATRP experiments at 80 °C indicated DMF as the best solvent. The effects of catalyst, monomer, and initiator concentrations were also examined. The livingness of the polymerization was studied by chain extension and electrochemical temporal control of polymerization.
- University of Padua Italy
- University of Coimbra Portugal
eATRP, styrene; eATRP; temporal control; copper catalyst, styrene, temporal control, <i>e</i>ATRP, copper catalyst
eATRP, styrene; eATRP; temporal control; copper catalyst, styrene, temporal control, <i>e</i>ATRP, copper catalyst
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