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Science Advances
Article . 2024 . Peer-reviewed
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Research Collection
Article . 2024
License: CC BY NC
https://dx.doi.org/10.48550/ar...
Article . 2024
License: arXiv Non-Exclusive Distribution
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Dehydration drives damage in the freezing of brittle hydrogels

Authors: Shaohua Yang; Dominic Gerber; Yanxia Feng; Nicolas Bain; Matthias Kuster; Laura de Lorenzis; Ye Xu; +2 Authors
APC: 3,833.88 EUR

Dehydration drives damage in the freezing of brittle hydrogels

Abstract

It is widely known that freezing breaks soft, wet materials. However, the mechanism underlying this damage is still not clear. To understand this process, we freeze model, brittle hydrogel samples, while observing the growth of ice-filled cracks that break these apart. We show that damage is not caused by the expansion of water upon freezing or the growth of ice-filled cavities in the hydrogel that exert pressure on the surrounding material. Instead, local ice growth dehydrates the adjacent hydrogel, leading to drying-induced fracture. This dehydration is driven by the process of cryosuction, whereby undercooled ice sucks nearby water toward itself, feeding ice growth. Our results highlight the strong analogy between freezing damage and desiccation cracking, which we anticipate being useful for developing an understanding of both topics. Our results should also give useful insights into a wide range of freezing processes, including cryopreservation, food science, and frost heave.

Country
Switzerland
Keywords

Condensed Matter - Materials Science, Soft Condensed Matter (cond-mat.soft), Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences, Physical and Materials Sciences, Condensed Matter - Soft Condensed Matter

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    selected citations
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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    28
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
28
Top 10%
Top 10%
Top 10%
Green
gold