The main purpose of this paper is to investigate the curvature behavior of four-dimensional shrinking gradient Ricci solitons. For such a soliton $M$ with bounded scalar curvature $S$, it is shown that the curvature operator $\text{Rm}$ of $M$ satisfies the estimate $|\text{Rm}|\leqslant cS$ for some constant $c$. Moreover, the curvature operator $\text{Rm}$ is asymptotically nonnegative at infinity and admits a lower bound $\text{Rm}\geqslant -c(\ln (r+1))^{-1/4}$, where $r$ is the distance function to a fixed point in $M$. As an application, we prove that if the scalar curvature converges to zero at infinity, then the soliton must be asymptotically conical. As a separate issue, a diameter upper bound for compact shrinking gradient Ricci solitons of arbitrary dimension is derived in terms of the injectivity radius.