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Magnetic susceptibility and Verdet constant in rare earth trifluorides

Authors: C. Leycuras; H. Le Gall; M. Guillot; A. Marchand;

Magnetic susceptibility and Verdet constant in rare earth trifluorides

Abstract

On three fluorides CeF3, NdF3, and PrF3 accurate susceptibilities measurements are reported from 2 up to 300 K under a magnetic field applied along the c axis. On the same samples, the optical Faraday rotation has been investigated in the temperature range 8–300 K at 0.6328 μm wavelength in a magnetic field up to 20 kOe. The reciprocal susceptibilities χ−1(T) follow a Curie Weiss law for T>100 K; the observed values of the paramagnetic Curie temperature are − 56 K (PrF3), − 114 K (CeF3), and − 26 K (NdF3). For T<100 K, strong crystalline field effects are evidenced: for example, a maximum of χ near 60 K has been found in PrF3. In the three fluorides negative Verdet constants have been obtained. The ratio V/χ appears as strongly temperature dependent, that is quite different from the theoretical prediction. Furthermore, the experimental results show an evidence of two behaviors of V/χ for T>77 K. (V and χ are expressed in deg cm−1 Oe−1 and in μB mol−1 Oe−1, respectively.) On one hand for NdF3 and PrF3, it has been found V/χ =A(1+αT) where A is a constant (−4320 in NdF3; −7241 in PrF3); in both samples, α is in the order of −6×10−4 K−1, note that Faraday rotation measurements performed at 0.4579 and at 0.5017 μm lead to an identical α value. On the other hand in CeF3, V/χ is a linear function of T−1 and is given by 13700(1+75.9/T).

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
56
Top 10%
Top 1%
Top 10%
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