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Assignment in the near-threshold absorption spectrum of N2

Authors: Hélène, Lefebvre-Brion;

Assignment in the near-threshold absorption spectrum of N2

Abstract

The absorption spectrum of N2, just above the first ionization limit, in the region between 125 750 and 126600cm−1, is dominated by two broad features which have the appearence of the towers of a “cathedral.” Recently, this energy region has been measured by Sommavilla et al. [J. Phys. B 35, 3901 (2002)] with a resolution of 0.04cm−1 and an assignment for one of these two bands has been suggested. In order to discuss this assignment, we have solved the coupled-channel Schrödinger equation with the parameters of Spelsberg and Meyer above the v=28 level of the b′∑u+1 state for determining the high levels of b′. Furthermore, we evaluate the autoionization widths and the rotational structure of the different possible assignments. Finally, we propose as assignment for the second tower of the cathedral the Rydberg state (AΠu2v+=1)3′d′σgΠu1.

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Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
22
Average
Top 10%
Top 10%
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