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Mixed-Lanthanoid Metal–Organic Framework for Ratiometric Cryogenic Temperature Sensing

descriptionPublicationkeyboard_double_arrow_right Article 24 Nov 2015 Netherlands English Publisher:American Chemical Society (ACS)Journal:Inorganic Chemistry, volume 54, pages 11,323-11,329 (issn: 0020-1669, eissn: 1520-510X,

Authors: Liu, X.; Akerboom, S.; Jong, M. de; Mutikainen, I.; Tanase, S.; Meijerink, A.; Bouwman, E.;

doi: 10.1021/acs.inorgchem.5b01924

pmid: 26599972

handle: 11245/1.508109 , 1887/3197570

Mixed-Lanthanoid Metal–Organic Framework for Ratiometric Cryogenic Temperature Sensing

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Abstract

A ratiometric thermometer based on a mixed-metal Ln(III) metal-organic framework is reported that has good sensitivity in a wide temperature range from 4 to 290 K and a quantum yield of 22% at room temperature. The sensing mechanism in the europium-doped compound Tb0.95Eu0.05HL (H4L = 5-hydroxy-1,2,4-benzenetricarboxylic acid) is based not only on phonon-assisted energy transfer from Tb(III) to Eu(III) centers, but also on phonon-assisted energy migration between neighboring Tb(III) ions. It shows good performance in a wide temperature range, especially in the range 4-50 K, reaching a sensitivity up to 31% K(-1) at 4 K.

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	citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	172
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