Synthesis, characterization, photophysical and photochemical properties of zinc and indium phthalocyanines bearing a vanillylacetone moiety known as an anticarcinogenic agent

descriptionPublicationkeyboard_double_arrow_right Article 01 Apr 2015 Turkey English Publisher:Elsevier BVJournal:Polyhedron, volume 90, pages 183-196 (issn: 0277-5387,

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Authors: Kıyak, Bülent; Esenpınar, Aliye Aslı; Bulut, Mustafa;

doi: 10.1016/j.poly.2015.01.043

handle: 11424/238353 , 20.500.11857/3540

Synthesis, characterization, photophysical and photochemical properties of zinc and indium phthalocyanines bearing a vanillylacetone moiety known as an anticarcinogenic agent

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Abstract

Abstract The synthesis of novel peripherally/non-peripherally tetra and octa vanillylacetone-substituted zinc and indium phthalocyanines was performed by cyclotetramerization of 4-[2-methoxy-4-(3-oxobutyl)phenoxy]phthalonitrile ( 1 )/3-[2-methoxy-4-(3-oxobutyl)phenoxy]phthalonitrile ( 2 ) and 4,5-bis[2-methoxy-4-(3-oxobutyl)phenoxy]phthalonitrile ( 3 ). The novel chromogenic compounds were characterized by elemental analysis, 1 H NMR, mass spectra, FT-IR and UV–Vis spectral data. The effects of the zingerone units on the zinc and indium phthalocyanine complexes ( 4 – 9 ) were also investigated.

Country

Turkey

Related Organizations

Marmara University
Turkey
Kırklareli University
Turkey

Keywords

COMPLEX, Singlet oxygen, Phthalocyanine, SENSOR, Vanillylacetone, Fluorescence quenching, PHOTODYNAMIC THERAPY, ZINGERONE, PORPHYRIN, PHOTOSENSITIZERS, Zingerone, METAL-FREE, SYSTEM

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