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Gold Bulletin
Article
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Gold Bulletin
Article . 2002 . Peer-reviewed
License: Springer Nature TDM
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Catalysis by Gold Nanoparticles

Authors: Grisel, Ruud; Weststrate, Kees-Jan; Gluhoi, Andrea; Nieuwenhuys, Bernard E;

Catalysis by Gold Nanoparticles

Abstract

Gold catalysts have superior activity in CO and other oxidations at low temperatures. Both a small (~ 5nm) particle size and the presence of a partly reducible oxide (ceria or a transition metal oxide) have a beneficial effect on the catalyst performance. The present paper reviews our recent studies focused on understanding the specific role of the Au particle size and that of the oxide (MO). Our personal viewpoint on gold catalysis is outlined. The effects of Au particle size and of the oxidic additive are distinguished by using several alumina-supported gold catalysts having different gold particle sizes and various oxidic additives. The most active catalyst in CO oxidation is the multicomponent catalyst Au/MgO/MnOx/Al2O3 with MgO being a stabilizer for the Au particle size and MnOx being the cocatalyst. This catalyst also exhibits good performance in selective oxidation of CO in a hydrogen atmosphere, a reaction relevant for the development of polymer electrolyte fuel cell technology.

Keywords

Inorganic Chemistry, Materials Science(all)

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
169
Top 10%
Top 1%
Top 10%
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