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Other literature type . 1970
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Communications in Mathematical Physics
Article . 1970 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
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The van der Waals limit for classical systems

III. Deviation from the van der Waals-Maxwell theory
Authors: Gates, D. J.; Penrose, O.;

The van der Waals limit for classical systems

Abstract

We examine the limiting free energy density $$a(\varrho ,0 + ) \equiv \mathop {\lim }\limits_{\gamma \to 0} a(\varrho ,\gamma )$$ of a classical system of particles with the two-body potentialq(r)+γ v K (γr), at density ϱ inv dimensions. Starting from a variational formula fora(ϱ, 0 + ), obtained in Part I of these papers, we obtain a new upper bound ona(ϱ, 0 + ) given by $$a(\varrho ,0 + ) \mathbin{\lower.3ex\hbox{$\buildrel<\over{\smash{\scriptstyle=}\vphantom{_x}}$}} CE\{ ME[a^0 (\varrho ) + {\textstyle{1 \over 4}}\tilde K_{\min } \varrho ^2 ] + ({\textstyle{1 \over 2}}\alpha - {\textstyle{1 \over 4}}\tilde K_{\min } )\varrho ^2 \} $$ . HereM E f, called the mid-point envelope off, is defined for any functionf by $$MEf(\varrho ) \equiv \mathop {\inf }\limits_h {\textstyle{1 \over 2}}[f(\varrho + h) + f(\varrho - h)];$$ C E f, called the convex envelope off, is defined for anyf as the maximal convex function not exceedingf; also α ≡ ed s K(s) and $$\tilde K_{\min } $$ is the minimum of the Fourier transform ofK, whilea 0(ϱ) is the free energy density forK = 0. For the class of functionsK such that $$\tilde K_{\min } $$ < 0 and $$\tilde K_{\min } $$ <2α, we deduce from this upper bound thata(ϱ, 0 + )

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
34
Average
Top 10%
Top 10%
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