Selective Electrocatalytic Oxidation of Sorbitol to Fructose and Sorbose

descriptionPublicationkeyboard_double_arrow_right Article 14 Nov 2014 Korea (Republic of), Netherlands English Publisher:WileyJournal:ChemSusChem, volume 8, pages 970-973 (issn: 1864-5631, eissn: 1864-564X,

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Authors: Kwon, Y.; Jong, E. de; Waal, J.K. van der; Koper, M.T.M.;

doi: 10.1002/cssc.201402880

pmid: 25400261

handle: 1887/3196758

Selective Electrocatalytic Oxidation of Sorbitol to Fructose and Sorbose

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Abstract

AbstractA new electrocatalytic method for the selective electrochemical oxidation of sorbitol to fructose and sorbose is demonstrated by using a platinum electrode promoted by p‐block metal atoms. By the studying a range of C4, C5 and C6 polyols, it is found that the promoter interferes with the stereochemistry of the polyol and thereby modifies its reactivity.

Countries

Korea (Republic of), Netherlands

Related Organizations

UNIST (Ulsan National Institute of Science and Technology)
Korea (Republic of)
Leiden University
Netherlands

Keywords

promotion, Fructose, Catalysis, fructose, heterogeneous catalysis, Isomerism, sorbitol, Electrochemistry, electrocatalysis, Sorbitol, Sorbose, Oxidation-Reduction, Platinum

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