Presented is an assessment of the on-orbit radiometric performance of the thermal emissive bands (TEB) of the Suomi National Polar-orbiting Partnership (S-NPP) Visible Infrared Imaging Radiometer Suite (VIIRS) instrument based on data from the first 2 years of operations—from 20 January 2012 to 20 January 2014. The VIIRS TEB are calibrated on orbit using a V-grooved blackbody (BB) as a radiance source. Performance characteristics trended over the life of the mission include the F factor—a measure of the gain change of the TEB detectors; the Noise Equivalent differential Temperature (NEdT)—a measure of the detector noise; and the detector offset and nonlinear terms trended at the quarterly performed BB warm-up cool-down cycles. We find that the BB temperature is well controlled and stable within the 30mK requirement. The F factor trends are very stable and showing little degradation (within 0.8%). The offsets and nonlinearity terms are also without noticeable drifts. NEdT is stable and does not show any trend. Other TEB radiometric calibration-related activities discussed include the on-orbit assessment of the response versus scan-angle functions and an approach to improve the M13 low-gain calibration using onboard lunar measurements. We conclude that all the assessed parameters comply with the requirements, and the TEB provide radiometric measurements with the required accuracy.