AbstractThe first measurement of the multiplicity dependence of intra-jet properties of leading charged-particle jets in proton–proton (pp) collisions is reported. The mean charged-particle multiplicity and jet fragmentation distributions are measured in minimum-bias and high-multiplicity pp collisions at center-of-mass energy $$\sqrt{s}$$ s = 13 TeV using the ALICE detector. Jets are reconstructed from charged particles produced in the midrapidity region ($$|\eta | < 0.9$$ | η | < 0.9 ) using the sequential recombination anti-$$k_{\textrm{T}}$$ k T algorithm with jet resolution parameters R = 0.2, 0.3, and 0.4 for the transverse momentum ($$p_\textrm{T}$$ p T ) interval 5–110 GeV/c. The high-multiplicity events are selected by the forward V0 scintillator detectors. The mean charged-particle multiplicity inside the leading jet cone rises monotonically with increasing jet $$p_\textrm{T}$$ p T in qualitative agreement with previous measurements at lower energies. The distributions of jet fragmentation function variables $$z^{\textrm{ch}}$$ z ch and $$\xi ^{\textrm{ch}}$$ ξ ch are measured for different jet-$$p_\textrm{T}$$ p T intervals. Jet-$$p_\textrm{T}$$ p T independent fragmentation of leading jets is observed for wider jets except at high- and low-$$z^{\textrm{ch}}$$ z ch values. The observed “hump-backed plateau” structure in the $$\xi ^{\textrm{ch}}$$ ξ ch distribution indicates suppression of low-$$p_\textrm{T}$$ p T particles. In high-multiplicity events, an enhancement of the fragmentation probability of low-$$z^{\textrm{ch}}$$ z ch particles accompanied by a suppression of high-$$z^{\textrm{ch}}$$ z ch particles is observed compared to minimum-bias events. This behavior becomes more prominent for low-$$p_\textrm{T}$$ p T jets with larger jet radius. The results are compared with predictions of QCD-inspired event generators, PYTHIA 8 with Monash 2013 tune and EPOS LHC. It is found that PYTHIA 8 qualitatively reproduces the jet modification in high-multiplicity events except at high jet $$p_\textrm{T}$$ p T . These measurements provide important constraints to models of jet fragmentation.