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Stoichiometry and Kinetics of Hydroxyl Radicals in Air Quality

Authors: García Raurich, Josep; Torres Lerma, Jose Antonio; Monagas Asensio, Pedro; Martínez Vimbert, Roberto; Arañó Loyo, Mariona; Martínez Roldán, Tania;

Stoichiometry and Kinetics of Hydroxyl Radicals in Air Quality

Abstract

The environmental health that nature offers us every day is closely linked to the sanitization provided by atmospheric chemistry, due to the oxidative processes that occur under the powerful sunlight passing through the clouds and reaching the forests, oceans, and seas, performs the multiple reactions, recombinations, mineralizations, degradations etc. in the atmosphere. It is a chain reaction called Open Air Factor (OAF) that cleans and disinfects the environment in which all living beings live called the biosphere. There are technologies and elements necessary to be able to imitate nature in this process of environmental sanitization for indoor environments based precisely on the Open Air Factor (OAF), and for this, for a question of safety and efficiency, it is necessary to measure the quantitative proportions or mass ratios of the chemical elements involved and that are involved in this natural chemical reaction, as well as to study the proportion of the various resulting elements and the composition of chemical mixtures of the components. The comparison of this stoichiometry that nature provides us with similar artificial systems for interiors will give us a vision of how similar the processes and resultants are. This paper is based on the stoichiometry and kinetics of hydroxyl radicals emitted by a device technologically based on the Open Air Factor (OAF) aimed at controlling indoor air quality. Specifically, it has been the analysis of the decay of the number of molecules of hydroxyl radicals (OH·) when reacting in the presence of typical air pollutants such as CO2, hydrocarbons and bicarbonate ions. These amounts of hydroxyl radical molecules (OH·) under study, unlike the multiple reactants that exist in Nature, have been generated with only two reactants, hydrogen peroxide and ozone, following current international safety regulations regarding their emissions in the presence of people.

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Spain
Keywords

Atmospheric chemistry, Reactive oxygen species (ROS), Indoor air pollution, Volatile Organic Compounds (VOC's), Advanced Oxidation Process (AOP's, Indoor Air Quality (IAQ), reactive oxygen species (ROS's), Reactive oxygen species (ROS)., Indoor Air Pollution (IAP), Química atmosfèrica, Volatile Organic Compounds (VOC), Open Air Factor (OAF), Hydroxyl radicals (OH·), Indoor Air Quality (IAQ), Àrees temàtiques de la UPC::Enginyeria química::Química del medi ambient, Hydroxyl radicals (OH), Advanced Oxidation Process (AOP), Contaminació de l'ambient interior

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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