Intermolecular vibrations are extremely challenging to describe but are the most crucial part for determining entropy and hence free energies, and enable for instance the distinction between different crystal-packing arrangements of the same molecule via THz spectroscopy. We introduce here a benchmark data set - V30 - containing 30 small molecular dimers with intermolecular interactions ranging from exclusively van-der-Waals dispersion to systems with hydrogen bonds. All calculations are performed with the gold standard of Quantum Chemistry CCSD(T). We discuss vibrational frequencies obtained via different models starting with the harmonic approximation over independent Morse oscillators up to second-order vibrational perturbation theory (VPT2), which allows a proper anharmonic treatment including coupling of vibrational modes. However, the large amplitude motions present in many low-frequency intermolecular modes are problematic for VPT2. In analogy to the often used treatment for internal rotations, we replace such problematic modes by a simple one-dimensional hindered rotor model. We compare selected dimers with available experimental data or high-level calculations of potential energy surfaces and show that VPT2 in combination with hindered rotors can yield a good description of fundamental frequencies for the discussed subset of dimers involving small and rigid molecules. This supporting dataset includes the calculated force constants, harmonic frequencies, Morse frequencies, VPT2 frequencies, and the optimized structures for the V30 dataset. See the included README.md file for more details. The related preprint can be found at https://doi.org/10.48550/arXiv.2209.04392.