The Nature and Composition of the Complexes of Uranium(VI), Vanadium(IV) and Iron (III) with Gallacetophenone

Department of Chemistry, University of Jammu, Jammu-180005 Department of Chemistry, Himachal Pradesh University, Simla-171001 Manuscript received 10 November 1975, accepted 10 February 1977 Gallacetophenone ( 2, 3, 4-trihydroxyacetophenone) combines with metal ions to form chelates. The molar ratios of the chelates with U(VI), V(IV) and Fe(III) in ethanol are found to be 1 : 1, 1 : 2 and 1 : 3. The solid complexes isolated from methanolic solutions have been found to conform to the formulae [UO2L(CH3OH)4 ]NO3, [VOL2] and [FeL3] where L is C3H7O4-. Tentative structures have been proposed for these complexes.

Keywords

Gallacetophenone, Nitrobenzene, Vanadium{IV), Uranium(VI)

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