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Leaching Experiments on UOX and MOX Spent Fuel: Results and Prospects of the SF-ALE Project at SCK CEN

Authors: Leinders, Gregory; Eysermans, Jan; Mennecart, Thierry; Cachoir, Christelle; Lemmens, Karel; Schreinemachers, Christian; Deissmann, Guido; +3 Authors

Leaching Experiments on UOX and MOX Spent Fuel: Results and Prospects of the SF-ALE Project at SCK CEN

Abstract

{"references": ["B.J. Lewis, W.T. Thompson, F.C. Iglesias, \"Fission Product Chemistry in Oxide Fuels\", in: R.J.M. Konings (Ed.) Comprehensive Nuclear Materials, Elsevier, Oxford, 2012, pp. 515-546.", "D. Cubicciotti, J.E. Sanecki, Journal of Nuclear Materials, 78 (1978) 96.", "H.J. Matzke, Radiation Effects, 53 (1980) 219.", "R.G.J. Ball, W.G. Burns, J. Henshaw, M.A. Mignanelli, P.E. Potter, Journal of Nuclear Materials, 167 (1989) 191.", "H. Kleykamp, Journal of Nuclear Materials, 171 (1990) 181.", "T.M. Besmann, J.W. McMurray, S. Simunovic, Calphad - Computer Coupling of Phase Diagrams and Thermochemistry, 55, Part 1 (2016) 47.", "E.H.P. Cordfunke, R.J.M. Konings, Journal of Nuclear Materials, 152 (1988) 301.", "R.W. Grimes, C.R.A. Catlow, Philosophical transactions - Royal Society. Mathematical, Physical and engineering sciences, 335 (1991) 609.", "H. Kleykamp, Journal of Nuclear Materials, 131 (1985) 221.", "L. Johnson, I. G\u00fcnther-Leopold, J. Kobler Waldis, H.P. Linder, J. Low, D. Cui, E. Ekeroth, K. Spahiu, L.Z. Evins, Journal of Nuclear Materials, 420 (2012) 54.", "E. Gonz\u00e1lez-Robles, et al., Journal of Nuclear Materials, 479 (2016) 67.", "D. Serrano-Purroy, F. Clarens, E. Gonz\u00e1lez-Robles, J.P. Glatz, D.H. Wegen, J. de Pablo, I. Casas, J. Gim\u00e9nez, A. Mart\u00ednez-Esparza, Journal of Nuclear Materials, 427 (2012) 249.", "D. Serrano-Purroy, I. Casas, E. Gonz\u00e1lez-Robles, J.P. Glatz, D.H. Wegen, F. Clarens, J. Gim\u00e9nez, J. de Pablo, A. Mart\u00ednez-Esparza, Journal of Nuclear Materials, 434 (2013) 451.", "K. Lemmens, et al., Journal of Nuclear Materials, 484 (2017) 307.", "T. Mennecart, G. Leinders, C. Cachoir, G. Cornelis, G. Verpoucke, G. Modolo, D. Bosbach, K. Lemmens, M. Verwerft, \"First phase of the Spent Fuel Autoclave Leaching Experiments (SF-ALE) at SCK\u2022CEN\", Global Top Fuel 2019, Seattle (USA) (2019).", "T. Mennecart, K. Lemmens, C. Cachoir, L. Adriaensen, A. Dobney, \"Leaching tests for the experimental determination of IRF radionuclides from Belgian high-burnup spent nuclear fuel: Overview of pre-test fuel characterization experimental set-up and first results\", 2nd Annual Workshop Proceedings of the Collaborative Project \"Fast/Instant Release of Safety Relevant Radionuclides from Spent Nuclear Fuel\", KIT Scientific report KIT- 7676, (2013).", "B. Kienzler, V. Metz, L. Duro, A. Valls, \"State of the art report - Update 2013 of the Collaborative Project Fast/Instant Release of Safety Relevant Radionuclides from Spent Nuclear (7th EC FP CP FIRST-Nuclides)\", (2013).", "L. Adriaensen, A. Dobney, P. Van Bree, \"Radiochemical burnup analysis of fuel sample FT1X57-D05-BU1\", SCK CEN Restricted contract report R-5640, (2014).", "Wieselquist, W.A., THE SCALE 6.2 ORIGEN API FOR HIGH PERFORMANCE DEPLETION (2015)."]}

Technical paper submitted for peer-review, accepted, and presented at the 2021 Topfuel conference (October 24-28, 2021). The conference was hosted as a hybrid event with on-site attendance (Santander, Spain) and remote attendance via a web application. ---Abstract--- In the context of interim or long-term storage of spent nuclear fuel, as well as in final disposal scenarios it is crucial to understand and accurately predict the materials��� behavior, specifically towards the release of radionuclides into the environment. Within the Spent Fuel Autoclave Leaching Experiments (SF-ALE) project at SCK CEN an improved experimental setup for performing leaching studies was developed, and six experiments (three on UOX fuel, three on MOX fuel) are being conducted in parallel over a timeframe of 36 months. To allow an accurate interpretation of the leaching data, depletion calculations were performed to establish the nuclide inventory of the MOX fuel samples at the time of the experiments. Preliminary results of the fission gas release measured during the leaching experiments are reported and discussed.

Country
Germany
Keywords

leaching, UOX, corrosion, MOX, spent nuclear fuel

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This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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