In this study, an innovative portable macro X-Ray Fluorescence (MA-XRF) scanner prototype has been employed in order to gain information on composition and distribution of corrosion products artificially grown on Cu-based coupons. First results have shown the importance of using artificially corroded reference samples before any assessment on archaeological artefacts. Moreover, the prototype used demonstrated to be a powerful tool for understanding complex corrosion processes which might occur on Cu-based alloys. The scanner was able to detect light elements as S and Cl, essential for studying the distribution of specific corrosion compounds. Using imaging techniques, it was possible to observe a gradient in Cu elemental maps intensity caused by the overlapping of a thicker corrosion product layer.