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International Journal of Advanced Research
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COPPER BIOSORPTION ON ARGAN NUT SHELL: KINETIC AND THERMODYNAMIC STUDIES

Authors: Boundati, Youssef El; Ziat, Khadija; Naji, Ahmed; Saidi, Mohamed; Rghioui., Lotfi;

COPPER BIOSORPTION ON ARGAN NUT SHELL: KINETIC AND THERMODYNAMIC STUDIES

Abstract

This work studies the adsorption of copper from aqueous solutions using Argan nut shell (ArNS) powders. ArNS was characterized by different techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and BET. The fractal-like kinetic models, and their classical counterparts, have been used to describe the kinetic adsorption of copper on ArNS. The modeling results show that the fractal-like kinetic models fit properly the kinetic data in comparison with the classical models. Thermodynamic quantities, such as Gibbs free energy (∆G?), the enthalpy (∆H?) and the entropy change of sorption (∆S?) have also been evaluated and it has been found that the sorption process was feasible, spontaneous and endothermic in nature. The reported findings indicate that Argan nut shell could be employed as a low-cost alternative adsorbent for efficient removal of copper ions from aqueous solutions.

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Keywords

Argan nut shell; Copper; Fractal-like kinetics; Liquid-solid biosorption; Mathematical modelling.

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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