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Conference object . 2018
License: CC BY NC ND
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Conference object . 2018
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On the correlation between volume change of anode materials in Li-ion cells and their degradation and failure

Authors: A. Kriston; V. Ruiz; A. Pfrang; A. Kersys; M. Marinaro; P. Stegmaier; C. Rahe; +2 Authors

On the correlation between volume change of anode materials in Li-ion cells and their degradation and failure

Abstract

Aiming at increasing the energy density of lithium ion batteries, a Si alloy/graphite blend was used as anode material, replacing traditional pure graphite anodes. For the first time an in-situ in-operando electrochemical dilatometry was used to evaluate the expansion and contraction of this novel Si-alloy anode materials during electrochemical cycling under constant temperature. The results show an increase in volume for the first cycle (80 %) with around 12 % irreversible expansion, while for graphite based anode these values are 10% and 3%, respectively. These volume variations require particular attention when producing commercial cells. As a complementary study, commercial 18650 cells with graphite anode were investigated and the mechanical effects – jelly roll deformation – after cycling were studied by X-ray computed tomography. The deformation found for graphite electrode elucidates the importance of understanding and quantifying swelling of Si electrodes for commercial cells.

Keywords

Li-ion battery; silicon anode; X-ray computed tomography; dilatometry; volume change.

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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