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Hydrocracking Of Oleic Acid Using Modified Niw/Sz-Mcm-41 To Produce Eco-Friendly Green Fuels

Authors: Ahmed M. Alsabagh, Sarah S.Selim, M. S. Elmelawy, M. A. Ebiad, Aly A. ALY, M. S. Behalob and Salwa A. Ghoneim*;

Hydrocracking Of Oleic Acid Using Modified Niw/Sz-Mcm-41 To Produce Eco-Friendly Green Fuels

Abstract

Oleic acid hydrocracking reactions have been investigated in a batch reactor over sulfide NiW/SZ-MCM-41 catalyst which was synthesized via the wet co-impregnation method. The catalyst was investigated by different instrumental techniques such as XRD, Textural surface properties, FE-SEM, HR-TEM, FT-IR and thermal analysis (TGA-DSC) techniques. Operating conditions of the hydrocracking reaction are; temperature= 425°C, pressure= 4 MPa, reaction Time = 2h, and catalyst weight%=5%. Quantitative gas chromatography detected n-paraffins and iso-paraffins ranging between C5–C18+ included C5-C8 gasoline range, C9-C14 kerosene range and C15-C18 diesel range. The product distribution of the organic liquid product contains 28.57% gasoline range (C5-C8), 53.88% kerosene range (C9-C14) and 16.83% diesel range (C15-C18). Distillation of OLP produced three distillates, gasoline (45-160ºC), kerosene (160-275ºC) and diesel (275-310ºC). The produced kerosene range has good properties compared with the properties of conventional kerosene. These properties made it qualified to use as a source of jet fuel production. Properties of the diesel range distillate obtained were favorable with the UOP –Hydro refining green diesel. The sulfided NiW/SZ-MCM-41catalyst is viewed as an interesting catalyst for the hydrocracking of fatty acid molecules into gasoline, kerosene, and diesel-range used as green fuel.

Keywords

Green fuels; Hydrocracking; MCM-41; transition metals; Sulfated zirconia; Oleic acid.

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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