{"references": ["F. Xie, W. Tian, M.P. Chipperfield, \"Radiative effect of ozone change\non stratosphere-troposphere exchange\", vol. 113, 2008, pp. D00B09,\ndoi: 10.1029/2008JD009829.", "V. Vaida, J.S. Daniels, H.G. Kjaergaard, L.M. Goss, A.F. Tuck,\n\"Atmospheric absorption of near infrared and visible solar radiation by\nthe hydrogen bonded water dimer,\" Q.J.R. Meteorol. Soc., vol. 127,\n2001, pp. 1627-1643.", "K.J. Bignell, \"The water vapour infrared continuum,\" Q.J.R. Meteorol.\nSoc., vol. 96, 1970, pp. 390-403.", "A.C.L. Lee, \"A study of the continuum absorption within the 8-13 um\natmospheric window,\" Q.J.R. Meteorol. Soc., vol. 99, 1973, pp.490-505.", "M.T. Coffey, \"Water vapour absorption in 10-12 um atmospheric\nwindow, \" Q.J.R. Meteorol. Soc., vol. 103, 1977, pp. 685-692.", "P.G. Wolynes, R.E. Roberts, \"Molecular interpretation of the infrared\nwater vapour continuum\", Applied Optics, vol. 17, 1978, pp. 1484-\n1485.", "H.R. Carlon , \"Do clusters contribute to the infrared absorption spectrum\nof water vapor?,\" Infrared Phys., vol. 19, 1979, pp. 549-557.", "H.A. Gebbie, \"Observations of anomalous absorption in the\natmosphere\", in Atmospheric water vapor, A. Deepak, T.D. Wilkerson\nand L.H. Ruhnke, Ed. New York: Academic Press, 1980, pp. 133-141.", "G.R. Low, H.G. Kjaergaard, \"Calculation of OH-stretching band intensities\nof the water dimer and trimer,\" J. Chem. Phys., vol. 110, 1999, pp. 9104-\n9115.\n[10] L.M. Goss, S.W. Sharpe, T.A. Blake, V. Vaida, and J.W. Brault, \"Direct\nabsorption spectroscopy of water clusters,\" J. Phys. Chem. A, vol. 103, 1999,\npp. 8620-8624.\n[11] J. Barrett, \"Greenhouse molecules, their spectra and function in the\natmosphere,\" Energy & Environment, vol. 16, 2005, pp. 1037-1045.\n[12] A.Y. Galashev, O.R. Rakhmanova, and V.N. Chukanov, \"Absorption and\ndissipation of infrared radiation by atmospheric water clusters,\" Russian Journal of\nPhysical Chemistry, vol. 79, 2005, pp. 1455-1159.\n[13] O.A. Novruzova, A.A. Galasheva, and A.E. Galashev, \"IR spectra of aqueous\ndisperse systems adsorbed atmospheric gases: 1. Nitrogen,\" Colloid Journal, vol.\n69, 2007, pp. 474-482.\n[14] O.A. Novruzova, and A.E. Galashev, \"Numerical simulation of IR\nabsorption, reflection, and scattering in dispersed water-oxigen media,\"\nHigh Temperature, vol. 46, 2008, pp. 60-68.\n[15] O.A. Novruzova, A.A. Galasheva, and A.E. Galashev, \"IR spectra of aqueous\ndisperse systems adsorbed atmospheric gases: 2. Argon,\" Colloid Journal, vol.\n69, 2007, pp. 483-491.\n[16] L.X. Dang, and T.M. Chang, \"Molecular dynamics study of water\nclusters, liquid and liquid-vapor interface of water with many-body\npotentials,\"J. Chem. Phys., vol. 106, 1997, pp. 8149-8159.\n[17] M.A. Spackman, \"Atom-atom potentials via electron gas theory,\" J.\nChem. Phys., vol. 85, 1986, pp. 6579-6585.\n[18] M.A. Spackman, \"A simple quantitative model of hydrogen bonding,\" J.\nChem. Phys., vol. 85, 1986, pp. 6587-6601.\n[19] J.M. Haile, Molecular Dynamics Simulation. Elementary Methods.\nN.Y.-Chichester-Brisbane-Toronto-Singapore: John Wiley & Sons,\nInc., 1992, ch. 4.\n[20] V.N. Koshlyakov, Zadachi Dinamiki Tverdogo Tela I Prikladnoi Teorii\nGiroskopov (Problems of Solid Body Dynamics and the Applied Theory\nof Gyroscopes). Moscow: Nauka, 1985, ch. 1.\n[21] R. Sonnenschein \"An Improved algorithm for molecular dynamics\nsimulation of rigid molecules,\" J. Comp. Phys., vol. 59, 1985, pp. 347-\n350.\n[22] M. Neumann, \"The dielectric constant of water. Computer simulations\nwith the MCY potential,\" J. Chem. Phys., vol. 82, 1985, pp. 5663-5672.\n[23] W.B. Bosma, L.E. Fried, S. J. Mukamel, \" Simulation of the\nintermolecular vibrational spectra of liquid water and water clusters,\" J.\nChem. Phys., vol. 98. 1993. pp. 4413-4421.\n[24] L.D. Landau, and E.M. Lifshitz, Elektrodinamika Sploshnykh Sred\n(Electrodynamics of Continuous Media). vol. 8, Moscow: Nauka, 1982.\n[25] Fizicheskaya Entsiklopediya (Physical Encyclopedia), vol. 1, A.M.\nProkhorov, Ed. Moscow: Sovetskaya entsiklopediya, 1988.\n[26] P.L. Goggin, and C. Carr, \"Far infrared spectroscopy and aqueous\nsolutions,\" in Water and Aqueous Solutions,vol, vol. 37, G.W. Neilson,\nJ.E.Enderby, Ed..Bristol: Adam Hilger, 1986, pp. 149-161.\n[27] G. Herzberg, Molecular Spectra and Molecular Structure: II. Infrared and\nRaman Spectra of Polyatomic Molecules.. Princeton: Van Nostrand Reinhold,\n1945.\n[28] V.I. Kozintsev, M.L. Belov, V.A. Gorodnichev, and Yu.V. Fedotov,\nLazernyi Optiko-akusticheskii Analiz Mnogokomponentnykh Gazovykh\nSmesei (Laser Optical Acoustic Analysis of Multicomponent Gas Mixtures),\nMoscow: Izd. MGTU im. N.E. Baumana, 2003.\n[29] Ph. Vallee, J. Lafait, M. Ghomi, M. Jouanne, J.F. Morhange, \"Raman\nscattering of water and photoluminescence of pollutants arising from\nsolid-water interaction,\" J. Mol. Struct. vol. 651-653. 2003, pp. 371-379.\n[30] S. J. Ghan, L. R. Leung, R. C. Easter, and H. Abdul-Razzak, \"Prediction\nof cloud droplet number in a general circulation model,\" J. Geophys.\nRes., vol. 102(D18), 1997, pp.777-794.\n[31] P.L. Kebabian, C.E. Kolb, A. Freedman, \"Spectroscopic water vapor\nsensor for rapid response measurements of humidity in the troposphere,\"\nJ. Geophys. Res. vol. 107(D23), 2002, pp. 4670 (1-14).\n[32] M.M. Halmann, M. Steinberg, Greenhouse Gas Carbon Dioxide\nMitigation. Science and Technology. Roca Raton, London, New York,\nWashington: Lewis publishers, 1999, pp. 7-8."]}

Absorption spectra of infra-red (IR) radiation of the disperse water medium absorbing the most important greenhouse gases: CO2 , N2O , CH4 , C2H2 , C2H6 have been calculated by the molecular dynamics method. Loss of the absorbing ability at the formation of clusters due to a reduction of the number of centers interacting with IR radiation, results in an anti-greenhouse effect. Absorption of O3 molecules by the (H2O)50 cluster is investigated at its interaction with Cl- ions. The splitting of ozone molecule on atoms near to cluster surface was observed. Interaction of water cluster with Cl- ions causes the increase of integrated intensity of emission spectra of IR radiation, and also essential reduction of the similar characteristic of Raman spectrum. Relative integrated intensity of absorption of IR radiation for small water clusters was designed. Dependences of the quantity of weight on altitude for vapor of monomers, clusters, droplets, crystals and mass of all moisture were determined. The anti-greenhouse effect of clusters was defined as the difference of increases of average global temperature of the Earth, caused by absorption of IR radiation by free water molecules forming clusters, and absorption of clusters themselves. The greenhouse effect caused by clusters makes 0.53 K, and the antigreenhouse one is equal to 1.14 K. The increase of concentration of CO2 in the atmosphere does not always correlate with the amplification of greenhouse effect.