Radio hot spots are bright and compact regions at the edges of powerful radio galaxies. In these regions the relativistic particles are reaccelerated by shocks produced by the interaction between the supersonic jets and the external environment. The discovery of synchrotron optical emission extending on kpc scale in some hot spots suggests that additional efficient and spatially distributed acceleration mechanisms must take place in order to compensate the severe radiative losses of optical emitting electrons. The key parameter to unveil the mechanism at work is the polarization intensity: high fractional polarization in the case of shocks, whereas low values or absence of polarization are expected in case of turbulence. \nIn this contribution I will present results on full-polarization ALMA observations at 97 GHz of the hot spot 3C 445 South. This arc-shaped hot spot is characterized by two main components enshrouded by extended emission that is visible from radio to X-rays. The ALMA results, complemented by mutiband VLA, VLT, HST and Chandra data, will be used to shed a light on the complex distribution and nature of particle acceleration at the edge of powerful radio galaxies.