Simple Formylation of Aromatic Compounds Using a Sodium Formate/Triphenylphosphine Ditriflate System

descriptionPublicationkeyboard_double_arrow_right Article 05 Jun 2017 English Publisher:Oxford University Press (OUP)Journal:Chemistry Letters, volume 46, pages 840-843 (issn: 0366-7022, eissn: 1348-0715,

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Authors: Mohammad M. Khodaei; Abdolhamid Alizadeh; Hadis Afshar Hezarkhani;

doi: 10.1246/cl.170152

Simple Formylation of Aromatic Compounds Using a Sodium Formate/Triphenylphosphine Ditriflate System

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Abstract

A new procedure was developed for formylation of arenes to produce aromatic aldehydes using a sodium formate/triphenylphosphine ditriflate system in ethanol at room temperature in good yields. The simplicity of the procedure, short reaction times, and mild reaction conditions are the other advantages of this metal- and carbon monoxide-free protocol.

Related Organizations

Razi University
Iran (Islamic Republic of)

Keywords

Formylation of arene, Metal- and CO-free protocol, Aromatic aldehyde

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