We present low-energy velocity map photoelectron imaging results for nitromethane anions. The photoelectron spectrum is interpreted with the aid of ab initio theory and Franck–Condon factor calculations. We obtain a new value for the adiabatic electron affinity of nitromethane of (172±6) meV and observe the dipole-bound state of nitromethane. The photoelectron angular distributions of the observed features are discussed in the context of threshold laws for photodetachment.