Phenylsilane as a safe, versatile alternative to hydrogen for the synthesis of actinide hydrides

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2015 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 51, pages 17,379-17,381 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Pagano, Justin K.; Dorhout, Jacquelyn M.; Waterman, Rory; Czerwinski, Kenneth R.; Kiplinger, Jaqueline L.;

doi: 10.1039/c5cc06856h

pmid: 26490094

Phenylsilane as a safe, versatile alternative to hydrogen for the synthesis of actinide hydrides

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Abstract

The thorium and uranium dihydride dimer complexes [(C 5 Me 5 ) 2 An(H)(μ-H)] 2 (An = Th, U) have been easily prepared using phenylsilane, which is an efficient and safer alternative to hydrogen gas.

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