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Materials Chemistry and Physics
Article . 2010 . Peer-reviewed
License: Elsevier TDM
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https://doi.org/10.31219/osf.i...
Article . 2018 . Peer-reviewed
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Phase transition and dielectric properties of BaTiO3 ceramics containing 10 mol% BaGeO3

Authors: Roberto Köferstein; Lothar Jäger; Mandy Zenkner; Stefan G. Ebbinghaus;

Phase transition and dielectric properties of BaTiO3 ceramics containing 10 mol% BaGeO3

Abstract

Dielectric properties and the cubic ? tetragonal phase transition temperature ofdense BaTiO3 ceramics containing 10 mol% BaGeO3, sintered between 840 and 1350 °C,have been investigated. The ceramic bodies were prepared from a nano-sized BaTi0.9/Ge0.1O3powder consisting of both BaTiO3 and BaGeO3 phases. The addition of BaGeO3 leads to areduction and broadening of the permittivity maximum, and to a small downshift of theparaelectric ? ferroelectric phase transition temperature, compared to a pure BaTiO3 ceramic.Lower sintering temperatures and thus small grain sizes of the ceramics cause an additionalreduction of the maximum permittivity down to 2800. Both DTA and dilatometricmeasurements reveal also a downshifting of the phase transition temperature, as well as adecrease of the latent heat.

Keywords

sintering, ceramic, DTA, permittivity, dilatometry, nano-particle, Inorganic Chemistry, Chemistry, BaTiO3, phase transition, Physical Sciences and Mathematics, Materials Chemistry, dielectric, perovskite

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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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