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Organic sorbents as barriers to decrease the mobility of herbicides in soils. Modelling of the leaching process

Authors: Marín-Benito, Jesús María; Sánchez-Martín, M. Jesús; Ordax, José M.; Draou, Khalid; Azejjel, Hanane; Rodríguez-Cruz, M. Sonia;

Organic sorbents as barriers to decrease the mobility of herbicides in soils. Modelling of the leaching process

Abstract

Abstract Numerous organic sorbents have been introduced in recent years to develop technologies aimed at preventing the pollution of soil and water by pesticides. This work set out to study and compare the effect on the mobility of ethofumesate and terbutryn in a soil of five low-cost organic residues (grape marc, pine wastes, urban solid wastes, sewage sludge, and spent mushroom substrate), and two organoclays (swelling and non-swelling clays modified with octadecyltrimethylammonium). Herbicide leaching experiments were conducted under water saturated flow in hand-packed soil columns in which sorbents were incorporated as barriers. The breakthrough curves obtained were fitted to the one-dimensional transport model CXTFIT. The leaching of ethofumesate and terbutryn in the soil recorded figures of 96.0% and 66.9%, respectively, and when a barrier of organic residues or organoclays was incorporated into the column these amounts decreased for ethofumesate to 65.7–84.6% and 3.35–5.99%, and for terbutryn to 0.28–13.8% and 1.11–0.79%. The effect of the organoclay barriers was more significant for ethofumesate, while the effect of organoclays for terbutryn was close to that of certain organic residues. The barrier's impact was also observed in the variation of the retardation coefficients (Rexp), which increased by 3–202 or 3–40 times those coefficients for soil without a barrier. Distribution coefficients (K) increased 72–147 and 3771–9461 times (ethofumesate), and 46–986 and 264–747 times (terbutryn) for amended soils with both organic residues and organoclays, respectively. Significant inverse correlations were found for ethofumesate between sorption coefficients and leached amounts due to the relevant effect of the OC content of organic sorbents in these processes, although this was not the case for terbutryn whose behavior was linked to the OC nature of organic sorbents. The herbicide leaching data were well described by CXTFIT (mean square error, MSE

Keywords

Ethofumesate, Organic sorbents, Modelling, CXTFIT, Soil columns, Terbutryn

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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