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Electrochimica Acta
Article . 2022 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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An electrochemical oscillatory flow reactor with pillar array electrodes improving mass transfer in electrosynthesis

Authors: Michiel Vranckaert; Hannes P.L. Gemoets; Ruben Dangreau; Koen Van Aken; Tom Breugelmans; Jonas Hereijgers;

An electrochemical oscillatory flow reactor with pillar array electrodes improving mass transfer in electrosynthesis

Abstract

Abstract: Synthetic organic electrochemistry, due to its advantages in terms of environmental impact and energy demand, has in the past years increasingly attracted researchers and companies. Consequently, a variety of (commercially available) electrochemical reactors have been developed. However, the focus remained on conducting fundamental electrochemical research rather than on scalability and productivity. In this work, we present a novel electrochemical reactor concept by applying an oscillatory flow regime in a reactor fitted with conductive pillar field electrodes which serve both as electroactive interface and turbulence promotor. The use of this electrochemical oscillatory flow reactor (eOFR) enabled the control and improvement of mass transfer, irrespective of residence time. This resulted in current densities rise up to 4-fold versus conventional steady state flow regimes and as such, this novel reactor bridges the gap between fundamental research and industrial applications.

Country
Belgium
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Keywords

Chemistry, Physics, Engineering sciences. Technology

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
13
Top 10%
Average
Top 10%
Green
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