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doi: 10.1002/ange.202113451 , 10.1002/anie.202113451 , 10.5281/zenodo.14639750 , 10.5281/zenodo.14639749
handle: 10550/80751 , 10261/266171
pmid: 34672406
pmc: PMC9298809
doi: 10.1002/ange.202113451 , 10.1002/anie.202113451 , 10.5281/zenodo.14639750 , 10.5281/zenodo.14639749
handle: 10550/80751 , 10261/266171
pmid: 34672406
pmc: PMC9298809
AbstractRuddlesden‐Popper lead halide perovskite (RP‐LHP) nano‐nanostructures can be regarded as self‐assembled quantum wells or superlattices of 3D perovskites with an intrinsic quantum well thickness of a single or a few (n=2‐4) lead halide layers; the quantum wells are separated by organic layers. They can be scaled down to a single quantum well dimension. Here, the preparation of highly (photo)chemical and colloidal stable hybrid LHP nanosheets (NSs) of ca. 7.4 μm lateral size and 2.5 nm quantum well height (thereby presenting a deep blue emission at ca. 440 nm), is reported for the first time. The NSs are close‐lying and they even interconnect when deposited on a substrate. Their synthesis is based on the use of the p‐toluenesulfonic acid/dodecylamine (pTS/DDA) ligand pair and their (photo)chemical stability and photoluminescence is enhanced by adding EuBr2 nanodots (EuNDs). Strikingly, they can be preserved as a solid and stored for at least one year. The blue emissive colloid can be recovered from the solid as needed by simply dispersing the powder in toluene and then using it to prepare solid films, making them very promising candidates for manufacturing devices.
Col·loides, Nanoestructures, General Chemistry, General Medicine, Catalysis, Communications, col·loides, nanoestructures, MAG: Photoluminescence, MAG: Materials science, MAG: Superlattice, MAG: Halide, MAG: Colloid, MAG: Chemical engineering, MAG: Phase (matter), MAG: Nanodot, MAG: Quantum well, MAG: Perovskite (structure)
Col·loides, Nanoestructures, General Chemistry, General Medicine, Catalysis, Communications, col·loides, nanoestructures, MAG: Photoluminescence, MAG: Materials science, MAG: Superlattice, MAG: Halide, MAG: Colloid, MAG: Chemical engineering, MAG: Phase (matter), MAG: Nanodot, MAG: Quantum well, MAG: Perovskite (structure)
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| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Top 10% |
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