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Ruddlesden–Popper Hybrid Lead Bromide Perovskite Nanosheets of Phase Pure n=2: Stabilized Colloids Stored in the Solid State

Authors: Rita B. Cevallos-Toledo; Ignacio Rosa-Pardo; Dr. Raul Arenal; Dr. Víctor Oestreicher; Michael Fickert; Dr. Gonzalo Abellán; Dr. Raquel E. Galian; +1 Authors

Ruddlesden–Popper Hybrid Lead Bromide Perovskite Nanosheets of Phase Pure n=2: Stabilized Colloids Stored in the Solid State

Abstract

AbstractRuddlesden‐Popper lead halide perovskite (RP‐LHP) nano‐nanostructures can be regarded as self‐assembled quantum wells or superlattices of 3D perovskites with an intrinsic quantum well thickness of a single or a few (n=2‐4) lead halide layers; the quantum wells are separated by organic layers. They can be scaled down to a single quantum well dimension. Here, the preparation of highly (photo)chemical and colloidal stable hybrid LHP nanosheets (NSs) of ca. 7.4 μm lateral size and 2.5 nm quantum well height (thereby presenting a deep blue emission at ca. 440 nm), is reported for the first time. The NSs are close‐lying and they even interconnect when deposited on a substrate. Their synthesis is based on the use of the p‐toluenesulfonic acid/dodecylamine (pTS/DDA) ligand pair and their (photo)chemical stability and photoluminescence is enhanced by adding EuBr2 nanodots (EuNDs). Strikingly, they can be preserved as a solid and stored for at least one year. The blue emissive colloid can be recovered from the solid as needed by simply dispersing the powder in toluene and then using it to prepare solid films, making them very promising candidates for manufacturing devices.

Country
Spain
Keywords

Col·loides, Nanoestructures, General Chemistry, General Medicine, Catalysis, Communications, col·loides, nanoestructures, MAG: Photoluminescence, MAG: Materials science, MAG: Superlattice, MAG: Halide, MAG: Colloid, MAG: Chemical engineering, MAG: Phase (matter), MAG: Nanodot, MAG: Quantum well, MAG: Perovskite (structure)

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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