1,7-Electrocyclisation of non-stabilised azomethine ylides

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1998 English Publisher:Elsevier BVJournal:Tetrahedron Letters, volume 39, pages 3,267-3,268 (issn: 0040-4039,

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Authors: Andrea Arany; Paul W. Groundwater; Miklòs Nyerges;

doi: 10.1016/s0040-4039(98)00466-3

1,7-Electrocyclisation of non-stabilised azomethine ylides

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Abstract

Abstract Non-stablilised α,β;γ,δ-unsaturated azomethine ylides 3 were generated by the decarboxylation method from 3,3-diarylpropenals 1 and secondary amino acids 2 . 1,7-Electrocyclisation of these azomethine ylides, followed by a 1,5-hydrogen shift, gives 2,3-dihydro-1 H -2-benzazephines 4 .

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