
doi: 10.1007/bf00665050
When niobium is heated in static air, layers of oxides and nitrides form on the surface, depending on the temperature. At 1150–1500°C, a layer of solid Nb2O5 forms with linear growth kinetics. At 1500–1900°C, a layer of Nb2N forms under a two-phase layer of liquid oxide+solid NbO2. The two-phase oxide layer has linear growth kinetics, while the Nb2N layer has parabolic kinetics. Above 1900°C, successive layers of Nb2N, NbN, and liquid oxide form, with both nitrides exhibiting parabolic growth kinetics. The activation energies of layer growth are as follows: Q=105 kJ/mol for Nb2O5, 120 kJ/mol for the two-phase oxide layer, and 220 kJ/mol for Nb2N (Q for liquid oxide and NbN layer formation was not determined). Above 1500°C, the nitride layers are somewhat protective, in that they slow the oxide formation rate and prevent ignition.
| selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 3 | |
| popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Average | |
| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Average | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Average |
