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Magneto-Optical Properties of Materials Containing Divalent Europium

Authors: J. C. Suits; B. E. Argyle; M. J. Freiser;

Magneto-Optical Properties of Materials Containing Divalent Europium

Abstract

A variety of relatively transparent materials containing Eu+ + have become available, thus enabling a study to be made of the magneto-optical properties of the Eu+ + ion in widely different environments. The following materials are reviewed: Eu2SiO4 (orthorhombic structure with a ferromagnetic Curie temperature Tc of 7°K), dilute Eu+ + in CaF2 (fluorite structure), EuF2 (fluorite structure, Tc≈0), EuO−Al2O3−B2O3 glasses (Tc=0), EuSe (NaCl structure, Tc=7°K), and EuO (NaCl structure, Tc=69°K). We discuss the magneto-optical properties of the ``nonmagnetic'' materials (CaF2: Eu+ +, EuF2, Eu glasses) in terms of an intra-atomic 4f7→4f65d transition. Using this transition, calculation of the Faraday and Cotton-Mouton birefringence in EuF2 gives reasonable agreement with experiment. The magneto-optical properties of the ``magnetic materials'' (Eu chalcogenides) are discussed in terms of an interatomic (4f7) (4f7) → (4f6) (4f75d) transition. This transition gives reasonable agreement with the observed magnitudes of the magnetic absorption edge shifts in EuSe and EuO.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
117
Top 10%
Top 1%
Top 10%
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