QMSCC calculations on the thermal quenching of the uranate luminescence in uranium-doped tungstates with perovskite structure

descriptionPublicationkeyboard_double_arrow_right Article 15 Mar 1980 English Publisher:AIP PublishingJournal:The Journal of Chemical Physics, volume 72, pages 3,539-3,546 (issn: 0021-9606, eissn: 1089-7690,

Authors: K. C. Bleijenberg; P. A. Breddels;

doi: 10.1063/1.439616

QMSCC calculations on the thermal quenching of the uranate luminescence in uranium-doped tungstates with perovskite structure

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Abstract

QMSCC calculations have been performed on the thermal quenching of the uranate luminescence in perovskite-type compounds with compositions A2BW0.997U0.003O6(A2B=Ca2Mg, Sr2Mg, Ba2Mg, Ba2Ca, Ba2Sr or Ba2Ba). Using a three states SCC model the luminescence quenching could be described quantitatively. The model was checked for Ba2MgWO6–U by investigating the luminescence properties of Ba2MgWO6–Eu and Ba2MgWO6–Eu, U.

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