Saving energy loss through the conduction is the major goal for many advanced countries so superconductors are the essential material to achieve such these dreams . The present investigations were concerned by synthesis of pure BPSCCO (Bi0.5Pb0.5)2 Sr2Ca1Cu2O8 and its variant zirconium containing composites with general formula : Bi1+xZrxPbSr2Ca1Cu2Oz and , where x = 0.1 ,0.2 and 0.3 mole % respectively ,were prepared via soultion route (Freeze Drying Technique ) to obtain nano-product . ZrO2 has a limited effect on the main crystalline superconductive 2212-phase as x amount added increase as indicated in XRD measurements .SE-microscopy accompanied with EDX proved that, solution route was the best in the degree of homogneties and exact molar ratios . ZrO2 exhibits strong interactions on Raman spectral modes of 2212-phase . ZrO2 has a slight effect on Tc’s even with maximum addition x = 0.3 mole . Finally the application of ZrO2-nano-additives to the 2212-BPSCCO superconductors enhance the super-conduction mechanism and consequently save too much the amount of electricity loss on the main nets of electricity

European Chemical Bulletin, Vol 2, No 3 (2013): European Chemical Bulletin