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First examples of neutral rhenium(V) complexes with a novel semi-rigid ligand containing a P,N,N,S donor atom set: Synthesis, characterisation and crystal structure

Authors: Latapie, Laure; Le Gal, Julien; Hamaoui, Bassem; Jaud, Joël; Gressier, Marie; Benoist, Eric;

First examples of neutral rhenium(V) complexes with a novel semi-rigid ligand containing a P,N,N,S donor atom set: Synthesis, characterisation and crystal structure

Abstract

A new PN2S ligand, N-[2-(diphenylphosphino)phenyl]-2-[(S-trityl)acetylamino]ethanamide [Ph-P(Ph2)N2S(Trt)], was synthesised and reacted with ReV precursors. The reaction of both tritylated and detritylated ligands with ReOCl3(PPh3)2 gave the same expected neutral complex [ReO{Ph-P(Ph2)N2S}] (4) in good yield. An unexpected neutral and diamagnetic species, [ReN{Ph-P(Ph2)N2S(Trt)}] (5), has been isolated during the complexation of the tritylated ligand with ReNCl2(PPh3)2. The complexes, characterized by classical spectroscopic methods and X-ray analysis for 4, are the first examples of neutral semi-rigid-PN2S rhenium(V) complexes.

Keywords

[CHIM.MATE] Chemical Sciences/Material chemistry, Rhenium complexes, Matériaux, Crystal structure, Tetradentate PN2S ligand, Phosphine

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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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