For $q=p^r$ with a prime $p\ge 7$ such that $q \equiv 1$ or $19\pmod {30},$ the desarguesian projective plane $PG(2,q)$ of order $q$ has a unique conjugacy class of projectivity groups isomorphic to the alternating group $A_6$ of degree 6. For a projectivity group $Γ\cong A_6$ of $PG(2,q)$, we investigate the geometric properties of the (unique) $Γ$-orbit $\mathcal{O}$ of size 90 such that the 1-point stabilizer of $Γ$ in $\mathcal O$ is a cyclic group of order 4. Here $\mathcal O$ lies either in $PG(2,q)$ or in $PG(2,q^2)$ according as 3 is a square or a non-square element in $GF(q)$. We show that if $q\geq 349$ and $q\neq 421$, then $\mathcal O$ is a 90-arc, which turns out to be complete for $q=349, 409, 529, 601,661.$ Interestingly, $\mathcal O$ is the smallest known complete arc in $PG(2,601)$ and in $PG(2,661).$ Computations are carried out by MAGMA.

10 pages