
doi: 10.1021/ol027265y
pmid: 12509898
An advanced intermediate in the synthesis of the phytotoxins cornexistin and hydroxycornexistin has been synthesized. Sequential palladium-mediated sp(2)-sp(3) fragment coupling and ring-closing diene metathesis have been used to construct the nine-membered carbocyclic core found in the natural products. [reaction--see text]
Models, Molecular, Biological Factors, Molecular Structure, Herbicides, Fungi, Furans, Palladium
Models, Molecular, Biological Factors, Molecular Structure, Herbicides, Fungi, Furans, Palladium
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