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Modulation of Chiroptical and Photophysical Properties in Helicenic Rhenium(I) Systems: The Use of an N‐(Aza[6]helicenyl)‐NHC Ligand

descriptionPublicationkeyboard_double_arrow_right Article 10 Mar 2023 Poland, France, United Kingdom English Publisher:WileyJournal:Chemistry – A European Journal, volume 29 (issn: 0947-6539, eissn: 1521-3765, Copyright policy )Funded by:ANR | HEL-NHC, NSF | Exploring Response Proper...
Authors: Etienne S. Gauthier; Laura Abella; Elsa Caytan; Thierry Roisnel; Nicolas Vanthuyne; Ludovic Favereau; Monika Srebro‐Hooper; +3 Authors

doi: 10.1002/chem.202203477

pmid: 36645138

Modulation of Chiroptical and Photophysical Properties in Helicenic Rhenium(I) Systems: The Use of an N‐(Aza[6]helicenyl)‐NHC Ligand

Abstract

AbstractThe photophysical and chiroptical properties of a novel, chiral helicene‐NHC−Re(I) complex bearing an N‐(aza[6]helicenyl)‐benzimidazolylidene ligand are described, showing its ability to emit yellow circularly polarized luminescence. A comparative analysis of this new system with other helicene‐Re(I) complexes reported to date illustrates the impact of structural modifications on the emissive and absorptive properties.

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Poland, France, United Kingdom
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Keywords

Re(I)-N-heterocyclic carbene, Density functional calculations, long-lived phosphorescence, [CHIM] Chemical Sciences, circularly polarized emission, helicene

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    popularity
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    		 Top 10%
    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
11
Top 10%
Average
Top 10%
Green
hybrid
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