Microwave-Assisted Synthesis, Structure and Properties of a Nano-Double-Bowl-Like Heptanuclear Nickel(II) Cluster

descriptionPublicationkeyboard_double_arrow_right Article 07 May 2014 English Publisher:Springer Science and Business Media LLCJournal:Journal of Cluster Science, volume 25, pages 1,489-1,499 (issn: 1040-7278, eissn: 1572-8862,

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Authors: Qiu Ping Huang; Shu Hua Zhang; Hai Yang Zhang; Gui Li; Mei Chun Wu;

doi: 10.1007/s10876-014-0725-1

Microwave-Assisted Synthesis, Structure and Properties of a Nano-Double-Bowl-Like Heptanuclear Nickel(II) Cluster

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Abstract

A nano-double-bowl-like heptanuclear nickel cluster [Ni7(mmp)6(OH)6]2·(ClO4)2·12H2O (1, Hmmp is 2-methoxy-6-methyliminomethyl-phenol) has been synthesized through the microwave-assisted reaction of Ni(ClO4)2·6H2O with 2-hydroxy-3-methoxy-benzaldehyde (Hhmb) and methylamine in distilled water only 29 min. The core of the complex 1 can be described as a double-bowl-like, while the dodecanuclear water cluster stands on the bowl. The magnetic investigation shows that 1 displays very weak ferromagnetic coupling between NiII ions.

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Guilin University of Technology
China (People's Republic of)

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