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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Power Sou...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Journal of Power Sources
Article . 2013 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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In situ formation of a solid oxide fuel cell (SOFC) cermet anode by NiWO4 reduction

Authors: Edward M. Sabolsky; Phil Gansor; Engin Çiftyürek; Katarzyna Sabolsky; Chunchuan Xu; John W. Zondlo;

In situ formation of a solid oxide fuel cell (SOFC) cermet anode by NiWO4 reduction

Abstract

Abstract The presented work describes a process for producing a mixed-conducting SOFC cermet anode through the in situ reduction of a ternary oxide. A porous nickel tungstenate (NiWO 4 ) was screen-printed and bonded onto an yttrium-stabilized zirconia (YSZ) electrolyte-supported SOFC by treatment at 1000 °C for 1 h. An (La,Sr)MnO 3 /Ce 0.9 Gd 0.1 O 2 (LSM/GDC) was utilized as the cathode with the NiWO4 acting as the anode for the SOFC. The ∼1-cm diameter fuel cell with a ∼100-μm thick YSZ electrolyte was tested in H 2 fuel at 800 °C. During the insertion of the H 2 fuel, the NiWO 4 was reduced to form a Ni/WO x cermet composite that consisted of a fine mixture of Ni-nanoparticles dispersed over the porous WO x support structure. A maximum power density of ∼104 mW cm −2 was attained for the reduced NiWO 4 anode, even with an un-optimized and dense microstructure, on an electrolyte-supported cell. The power density was increased to ∼165 mW cm −2 with the incorporation of GDC powder into the NiWO 4 anode. The same NiWO 4 /GDC composite was tested within a fuel stream of H 2 containing 10 ppm PH 3 . The cell's degradation rate was 0.006 V h −1 for 5 h at 750 °C, which is similar to that observed for conventional Ni/YSZ cermets.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
9
Top 10%
Average
Average
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