Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1989 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
versions View all 2 versions
addClaim

This Research product is the result of merged Research products in OpenAIRE.

You have already added 0 works in your ORCID record related to the merged Research product.

Homology of interatomic forces and Debye temperatures in transition metals

Authors: Göran Grimvall; A. Fernández Guillermet;

Homology of interatomic forces and Debye temperatures in transition metals

Abstract

Using experimental data on the entropy S at intermediate temperatures, corrected for an electronic term to get the vibrational entropy, we obtain well-defined and accurate ``entropy Debye temperatures'' FTHETA=${\mathrm{FTHETA}}^{S}$. From ${\mathrm{FTHETA}}^{S}$ we define a quantity with the dimension of a force constant, ${k}^{S}$==M(${k}_{B}$FTHETA/\ensuremath{\Elzxh}${)}^{2}$, where M is the atomic mass. Similarly, data on the low-temperature vibrational heat capacity and the elastic coefficients yield Debye temperatures ${\mathrm{FTHETA}}^{C}$ and ${\mathrm{FTHETA}}^{\mathrm{elas}}$ and corresponding force constants ${k}^{C}$ and ${k}^{\mathrm{elas}}$. The ratios of ${k}^{S}$ for the 4d-5d pairs Zr,Hf, Nb,Ta, Mo,W, Tc,Re, Ru,Os, Rh,Ir, and Pd,Pt are remarkably constant, (${k}^{S}$${)}^{4d}$/(${k}^{S}$${)}^{5d}$ =0.76\ifmmode\pm\else\textpm\fi{}0.01, in spite of varying crystal structures. Further, (${k}^{C}$${)}^{4d}$/(${k}^{C}$${)}^{5d}$ =0.70\ifmmode\pm\else\textpm\fi{}0.07 and (${k}^{\mathrm{elas}{)}^{4d}/({k}^{\mathrm{elas}{)}^{5d}}}$ =0.69\ifmmode\pm\else\textpm\fi{}0.08. The corresponding force-constant ratios ${k}^{3d}$/${k}^{4d}$ vary more. This correlates with an approximately constant atomic-volume ratio ${\ensuremath{\Omega}}^{4d}$/${\ensuremath{\Omega}}^{5d}$=0.99\ifmmode\pm\else\textpm\fi{}0.02, while ${\ensuremath{\Omega}}^{3d}$/${\ensuremath{\Omega}}^{4d}$=0.81\ifmmode\pm\else\textpm\fi{}0.05 shows irregularities, mainly of magnetic origin. As a basis for our analysis, we review low-temperature Debye temperatures ${\mathrm{FTHETA}}^{\mathrm{elas}}$ and ${\mathrm{FTHETA}}^{C}$ and the bulk modulus B of the transition metals.

  • BIP!
    Impact byBIP!
    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    65
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
Powered by OpenAIRE graph
Found an issue? Give us feedback
citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
65
Top 10%
Top 10%
Top 10%
Related to Research communities
Upload OA version
Are you the author? Do you have the OA version of this publication?