Incipient carbon nanoparticles, CNP, formed by incomplete hydrocarbon combustion are composed of polycyclic aromatic hydrocarbons [1,2] and exhibit a quantum dot behavior [3], which make them ideal for a wide range of applications. Flame synthesis offers a continuous and low-cost process for the production of inorganic nanoparticles, such as TiO2, with fine control of cristallinity and phase. Likewise, carbon nanoparticles, CNPs, with tailored size and optical and electronic properties can be produced by optimizing the flame process. The assembly of nanoparticles into a uniform thin film with precise control over chemical and physical properties poses a significant challenge. Thermophoretic sampling relies on the thermophoretic forces driving the particles in the hot flame towards a cold substrate inserted in the flame and can be used to produce nanostructured, self-assembled films that can lead to novel applications. In this work, CNP and CNP/TiO2 nanoparticles have been produced in premixed ethylene-air flames and thin films have been realized by thermophoretic deposition on silicon substrates with gold interdigitated electrodes. Scanning mobility particle sizer furnished the particle size distribution and Raman and optical spectroscopy chemico-physical and structural information. The electrical characterization of the films was conducted by measuring the IV characteristics which shows a good linearity in the interval [-5 V, 5 V] whereas non-linear phenomena appear for wider voltage ranges and hysteresis phenomena are also observed in carbon/TiO2 films. Impedance spectroscopy was used to investigate the films with respect to their microstructure. This method is indeed particularly useful for nanostructured films with inter-grain and grain-edge impedances and capacities. Finally, noise spectral density at low and very low frequency was measured to investigate the electron transport. The main source of noise is of thermal type for the carbon material, whereas carbon/TiO2 film shows a Fliker type, 1/f noise, consistent to a larger amount of localized states responsible for trapping/detrapping processes of charge carriers and charge fluctuations during the conduction process. [1] Schulz, F., Commodo, M., Kaiser, K., De Falco, G., Minutolo, P., Meyer, G., D`Anna, A., Gross, L., "Insights into incipient soot formation by atomic force microscopy" Proc. Combust. Inst. 37: 885-892 (2019). [2] Commodo, M., Kaiser, K., De Falco, G., Minutolo, P., Schulz, F., D`Anna, A., Gross, L., "On the early stages of soot formation: molecular structure elucidation by high-resolution atomic force microscopy" Combust. Flame 205, pp. 154-164. [3] Liu, C, Singh, A.V., Saggese, C., Tang, Q., Chen, D., Wan, K., Vinciguerra, M., Commodo, M., De Falco, G., Minutolo, P., D'Anna, A., Wang H. , Flame-formed carbon nanoparticles exhibit quantum dot behaviors, 2019, DOI:10.1073/pnas.1900205116