Despite an increase in the process automation, different activities remain mainly operator driven, as the loading and unloading of tankers, maintenance operations, and so on. In these cases, the activities performed by the operator can be critical, both for the safety and for the product quality. Optimizing the operational procedures is thus a key factor for quality and safety. A risk assessment of the procedure can be adopted as a base for optimisation, highlighting which of the tasks within the procedure mainly contributes to the risk of the working activity. Usually the analysis of the procedures is carried on through a task analysis as in Builes et al. (2014). In this paper the task analysis is used as a starting point for a quantitative risk assessment carried on through an integrated dynamic decision analysis. The logical-probabilistic model of the procedure is elaborated jointly with a consequences analysis, obtaining a risk assessment for all the sequences of tasks of the work procedure under analysis. The risk assessment considered both possible equipment failures and the potential operational errors in executing the tasks. The proposed approach is in this paper demonstrated through the application of the integrated decision analysis for the operation of unloading of ammonia in a plant for the production and storage of fertilizers.