Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ BOA - Bicocca Open A...arrow_drop_down
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
addClaim

Thermally Regenerable Redox-Flow Batteries

Authors: FACCHINETTI, IRENE; Cobani, E; Brogioli, D; La Mantia, F; Ruffo, R;

Thermally Regenerable Redox-Flow Batteries

Abstract

A Thermally Regenerable redox-flow Batterie (TRB) is an electrochemical cell which produce electrical current by consuming solutions, with the same composition, but different concentrations. In this kind of device, the two solutions can be regenerated by distillation, exploiting low temperature heat (<100°C) produced in different industrial applications. The produced energy is extracted at the expenses of the mixing free energy of the two solutions. This cell stores energy in form of solutions and it will enable to convert heat from geothermal sources, industrial waste and solar heat collected by low-concentration optics, in a more efficient way then the traditional thermoelectrical converters. The efficiency of the whole device depends by the efficiency of the electrochemical cell and the efficiency of the distillation unit, which can be improved choosing a salt that gives a high boiling point elevation. An example of TRB is based on LiBr solutions, in which the different electrochemical equilibrium reached at the electrodes (Pt) lead to an efficient production of electrical current, with the passage of Li+ and production/consumption of Br2 and Br– at the electrodes. To equilibrate the bromine concentration (to extract the maximum energy possible), the solutions are pumped in a second device called “through liquid exchanger” which is based on the passage of bromine through an organic solvent in which LiBr and water are insoluble. A cell based on LiBr could provide 38,5 Wh/L starting from two solutions at 26% and 2.5% of molar fraction at room temperature.

Country
Italy
Related Organizations
Keywords

redox-flow, thermoelectrical convertion, low temperature heat, distillation, electrochemistry, concentration battery

  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    0
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Green