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Radboud Repository
Article . 2013
Data sources: Radboud Repository
Monthly Notices of the Royal Astronomical Society
Article . 2013 . Peer-reviewed
Data sources: Crossref
https://dx.doi.org/10.48550/ar...
Article . 2013
License: arXiv Non-Exclusive Distribution
Data sources: Datacite
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Effects of structural and chemical disorders on the vis/UV spectra of carbonaceous interstellar grains

Authors: Papoular, R.J.; Yuan, S.; Roldán, R.; Katsnelson, M.I.; Papoular, R.;

Effects of structural and chemical disorders on the vis/UV spectra of carbonaceous interstellar grains

Abstract

The recent spectacular progress in the experimental and theoretical understanding of graphene, the basic constituent of graphite, is applied here to compute, from first principles, the UV extinction of nano-particles made of stacks of graphene layers. The theory also covers cases where graphene is affected by structural, chemical or orientation disorder, each disorder type being quantitatively defined by a single parameter. The extinction bumps carried by such model materials are found to have positions and widths falling in the same range as the known astronomical 2175 Åfeatures: as the disorder parameter increases, the bump width increases from 0.85 to 2.5 $μ$m$^{-1}$, while its peak position shifts from 4.65 to 4.75 $μ$m$^{-1}$. Moderate degrees of disorder are enough to cover the range of widths of the vast majority of observed bumps (0.75 to 1.3 $μ$m$^{-1}$). Higher degrees account for outliers, also observed in the sky. The introduction of structural or chemical disorder amounts to changing the initial $sp^{2}$ bondings into $sp^{3}$ or $sp^{1}$, so the optical properties of the model material become similar to those of the more or less amorphous carbon-rich materials studied in the laboratory: a-C, a-C:H, HAC, ACH, coals etc. The present treatment thus bridges gaps between physically different model materials.

14 pages, 16 figures, to appear in MNRAS

Country
Netherlands
Keywords

Condensed Matter - Mesoscale and Nanoscale Physics, Theory of Condensed Matter, Astrophysics of Galaxies (astro-ph.GA), Mesoscale and Nanoscale Physics (cond-mat.mes-hall), FOS: Physical sciences, lines and bands [ISM], Astrophysics - Astrophysics of Galaxies, ISM: lines and bands, Astrochemistry

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
OpenAIRE UsageCountsViews provided by UsageCounts
downloads
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6
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